I was all ready to say "Hasbro won't make Headmasters in a deluxe!" and then remembered that Cyclonus got his Targetmaster...so who knows. There are some interesting names there. Some would likely be repaints as well, but that's expected. Of course without any info to back up this list I could make some half-assed guesses but I'm sure there's probably already a thread for that.
assembling a Neo-G1/TF:TM cast. Please PM if you have (or know of) the following at a reasonable price: Classics or Henkei Prowl, Astrotrain, Ramjet, Skywarp, Sunstreaker, Sideswipe, Blurr, Perceptor, GDO Wheelie and Springer, or 3rd Party Motobot Arcee, FP Springer, iGear Ratchet and Ironhide, City Commander (and/or Ultra Magnus), Starscream (deluxe) Coronation add-on, or Spike and Daniel in their Exo-Suits.